residue oil desulfurization using oxidation and extraction method
Patent Report: | US10081770 | Process for oxidative desulfurization and sulfone disposal using solvent deasphalting
Embodiments provide a method and apparatus for upgrading a hydrocarbon feedstock. According to at least one embodiment, the method includes the steps of (a) supplying a hydrocarbon feedstock to an oxidation reactor, wherein the hydrocarbon The method includes the steps of (a) supplying a hydrocarbon feedstock to an oxidation reactor, wherein the h Process for Oxidative Desulfurization and Denitrogenation Using A Fluid Catalytic Cracking (FCC) Unit - Saudi Arabian Oil Company Desulfurization of liquid fuels by air assisted peracid oxidation system in the presence of Fe-ZSM-5 as catalyst 2531 Korean J. Chem. Eng.(Vol. 33, No. 9) In the present work, we carried out ODS of model as well as real industrial oil fractions
Desulphurisation of Petroleum Coke by Solvent Extraction
In similar conditions, the sulphur compounds in vacuum gas oil were removed successfully by pre-oxidation and extraction by Shiraishi & Hirai [28]. In order to investigate the effects of pre-oxidation on the efficiency of desulphurization by Oleh karena demikian senyawa-senyawa tersebut tidak akan terlihat pada spektra kromatografi gas untuk tempe usia fermentasi 5 dan 8 hari dan menyebabkan jumlah komponen volatil flavor Isolation and Identification of Volatile Components in Tempe Flue-gas desulfurization (FGD) is a set of technologies used to remove sulfur dioxide (SO 2) from exhaust flue gases of fossil-fuel power plants, and from the emissions of other sulfur oxide emitting processes such as waste incineration.
Avocado Seeds: Extraction Optimization and Possible Use as Antioxidant in Food
best conditions of extraction of polyphenols from dried avocado seed. Second, an extract using these conditions was obtained and the effect of lyophilized powder in the delay oxidation in oil-in-water (O/W) emulsions and beef meat burgers A combination desulfurization method for diesel fuel: oxidation by ionic liquid with extraction by solvent Fuel 2018 224 545 551 10.1016/j.fuel.2018.03.108 2-s2.0-85044166515 17 Li T. Yamamoto D. Oxidative desulfurization of liquid fuels 39 This work presents the results obtained in the development of phosphotungstic acid/semi-coke catalysts in the oxidative desulfurization (ODS) process of diesel oil using hydrogen peroxide as the oxidizing agent. Phosphotungstic acid /semi-coke
A review of extractive desulfurization of fuel oils using ionic liquids - RSC Advances (RSC Publishing)
Some other desulfurization methods currently under study, such as extraction, oxidation, adsorption and biodesulfurization were also briefly outlined. It can be inferred that ILs remain a class of ideal solvents to realize clean fuel oil in the A method for obtaining oil products such as diesel fuel with improved quality, from a gas oil fraction containing organosulphur compounds such as dibenzenethiophenes and/or their derivatives, with initial and final boiling points generally 9/12/2020 · The oxidative desulfurization of five (5) model sulfur compounds and eleven (11) surrogate blends was investigated using the hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>)-acetic acid (CH<sub>3</sub>COOH)
A new approach in deep desulfurization of model fuel through integration of electrochemical oxidation and liquid-liquid extraction in a biphasic
10/6/2021 · A combination desulfurization method for diesel fuel: Oxidation by ionic liquid with extraction by solvent Fuel, 224 ( 2018 ), pp. 545 - 551, 10.1016/j.fuel.2018.03.108 Article Download PDF View Record in Scopus Google Scholar WO2012033778A1 PCT/US2011/050586 US2011050586W WO2012033778A1 WO 2012033778 A1 WO2012033778 A1 WO 2012033778A1 US 2011050586 W US2011050586 W US 2011050586W WO 2012033778 A1 WO201 Ultradeep desulfurization of model oil through the oxidative adsorption process using Dawson‐type polyoxometalates and graphene oxide multifunctional composites Shuai‐Yong Dou School of Environmental Science and Engineering, Shandong University,
Desulphurisation of Petroleum Coke by Solvent Extraction
An extraction using toluene gave an extract with a slight yellow colour which was apparently due to some oil which had been removed from the coke. It was evident that the oil adsorbed on the coke did not contain appreciable amounts of sulphur 22/6/2020 · Desulfurization of a model fuel (DBT, 4-MDBT and 4,6-DMDBT with 500 ppm S each) using UiO-66(Zr) samples with different crystallinities and H 2 O 2 as oxidant. The ODS system combines initial extraction (before dashed line) and catalytic step a promising new method for deep desulfurization of fossil oil.2 In ODS, refractory organosulfur compounds are usually oxidized to the corresponding sulfones which are then removed by extraction, adsorption, distillation, or decomposition.2,9 ODS
METHODS FOR DESULFURIZATION OF CRUDE OIL- A REVIEW. - Free Online Library
30/4/2016 · 2.9. Desulfurization by ultrasound oxidation Removal of sulfur compound from hydrocarbons by a method of oxidation followed by ultrasound is a useful method. This method required an energy which acquired from ultrasound. In this method the feed 15/6/2020 · The ODS reaction was carried out using a two-phase extraction-oxidation procedure. In a typical reaction, 40 mg NU-1000 was dispersed in 10 g acetonitrile in a 100 mL round bottom flask. To the dispersion, 10 g model oil (1000 ppmw S from DBT in Development and method validation for determination of Deltamethrin residue in olive oil using a reversed-phase high performance liquid chromatography Ikram Jaabiri1, Dalel Belhaj2*, Nesrine Turki3, Monem Kallel4, Habib Ayadi5, Mohieddine
STUDY ON HYDRODYNAMIC PARAMETERS OF THE OXIDATIVE DESULFURIZATION OF HIGH SULFUR STRAIGHT RUN OIL FRACTIONS
desulfurization process of straight-run kerosene (SRKF) and straight-run diesel fractions (SRDF) via oxidation of sulfuric organic compounds, followed by the removal of oxidation products. The established parameters which are characterized by ODS, in general, consists of two steps: (i) oxidation and (ii) extraction. The oxidation of sulfur compounds is carried out using a suitable catalyst (hereafter termed as an ODS catalyst) in the presence of an oxidant. Choosing a suitable ODS A photochemical oxidation and ionic liquid ([Bmim]PF6) extraction coupling technique was employed in deep desulphurization of light oil with the presence of photo oxidant H2O2. In this process, [Bmim]PF6 was utilized to be the extractant and
Deep desulfurization by oxidation using an active ionic liquid‐supported Zr metal–organic framework as catalyst, Applied Organometallic
1/1/2015 · In this study, a Zr metal–organic framework (UIO‐66) was synthesized with zirconium tetrachloride and terephthalic acid using the solvent method. Then various masses of 1‐methylimidazolium‐3‐propylsulfonate hydrosulfate (PSMIMHSO4) were Journal of Faculty of Engineering & Technology, 2007-2008, pages 47-56 Coal Desulfurization by Solvent Leaching Methods Ali Ahmed, Naseer Ahmad, Rizwan Shah, M. Naeem Bhatti, Mahmood Saleem1 ABSTRACT Coal desulfurization prior to usage is a Hydrodesulfurization (HDS) has been commercially employed for the production of ultra-low sulfur fuel oil. However, HDS is unable to remove sterically hindered sulfur-containing compounds such as dibenzothiophene (DBT) and benzothiophene (BT).
Desulfurization of Saudi Arabian crudes by oxidation–extraction method | SpringerLink
6/6/2015 · The oxidation–extraction desulfurization of Saudi Arabian crudes was conducted with hydrogen peroxide–acetic acid oxidation system. The selection of extractant, the optimization of oxidation–extraction conditions, and the exploration of desulfur Oxidative desulfurization (ODS) has been considered as a further new technology for deep desulfurization of light oil. This desulfurization process includes two stages: (i), oxidation in a first step; and (ii), liquid extraction at the end. It 28/10/2016 · 12-Tungstophosphoric acid (PW) supported on KSF montmorillonite, PW/KSF, was used as catalyst for deep oxidative desulfurization (ODS) of mixed thiophenic compounds in model oil and crude oil under mild conditions using hydrogen peroxide (H2O2)
Oxidative desulfurization of hydrocarbon raw materials, Russian Journal of General Chemistry | 10.1134/S1070363209060437 | DeepDyve
11/8/2009 · Zhou et al. [24] performed on the cobalt catalyst than on the molybdenum catalyst. catalytic oxidative desulfurization of dibenzothiophene in decalin using the oil-soluble oxidant cyclohexanone At high conversions of sulfur compounds, sulfones Desulfurization of diesel oil by selective oxidation and extraction of sulfur compounds by ionic liquids—a contribution to a competitive process design Andreas Seeberger, Andreas Jess Green Chemistry 2010 12 (4), 602 Oxidative desulfurization of gasoline was conducted in emulsion oxidative system (water –in-oil [W/O]) using hydrogen peroxide as the oxidizing agent, N-methyl-2-pyrrolidone (NMP) and water as extractive solvent, span60 as surfactant.
A study of the desulfurization selectivity of a reductive and extractive desulfurization process with sodium borohydride in polyethylene glycol
26/6/2020 · An oxidative desulfurization method using ultrasound Fenton's reagent for obtaining low and/or ultra-low sulfur diesel fuel. Fuel Process Technol. 89, 927–32 (2008). CAS Article Google Scholar The method includes the steps of (a) supplying a hydrocarbon feedstock to an oxidation reactor, wherein the hydrocarbon feedst Process for oxidative desulfurization and sulfone management by gasification - SAUDI ARABIAN OIL COMPANY claims a method of removing organic sulfur compounds from liquid oil using oxidizing agents, followed by distillation, and solvent extraction or adsorption.7 The aim of the present work was to carry out a comparative study of the benzothiophene
Petroleum and Coal - VÚRUP
Figure 1. The process flow diagram of oxidation/extraction and oxidation/adsorption desulfurization 2.4. Analysis method The sulfur content (wt %) of the two samples of crude oil was measured by SELFA-2800 sulfur analyzer manufactured by Horiba, Method for oxidative desulfurization of fossil fuels with ultrasound. The invention relates to a method for desulfurization of crude oil and fuel oil-based. The method includes the stage of combining the fuel with acidified aqueous solution Oxidative processes of desulfurization of liquid fuels Download Oxidative processes of desulfurization of liquid fuels Janita Butt Related Papers Application of Microorganisms to the Processing and Upgrading of Crude Oil and Fractions By Marcela